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330108

Sigma-Aldrich

Palladium on carbon

Evonik NOBLYST® P1173 10% Pd

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
Molecular Weight:
106.42
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

Quality Level

contains

~50% water

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

extent of labeling

10 wt. % loading (dry basis)

weight

Unit weight excludes weight of water

matrix

activated carbon, wet support

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

Pd/C is used as a catalyst for hydrogenation of ketones, alkynes, alkenes, nitriles, azides, imines, nitro groups, and heterocyclic aromatic compounds.

Application

Catalyst for:
  • Stille reaction
  • Hydrogenation reactions
  • Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
  • Deoxygenation
  • Oxidation reactions
  • Coupling reactions
Recent journal articles also use Pd/C for the following:
  • Transfer hydrogenation of aromatic nitro compounds to anilines in the presence of methanol as a green reductant.
  • N-Methylation of nitroarenes and amines.
  • Aminocarbonylation of aryl iodides to synthesize primary amides.
  • Direct C-2 arylation of indoles with arylboronic acids.
  • Synthesis of polyamides via carbonylation polycondensation reaction.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Legal Information

Noblyst is a registered trademark of Evonik Degussa GmbH

related product

Product No.
Description
Pricing

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

330108-DK:
330108-50G:
330108-250G:
330108-CH:
330108-VAR:
330108-10G:
330108-1KG:
330108-BULK:
330108-1G:


Certificates of Analysis (COA)

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Direct C-H bond activation: palladium-on-carbon as a reusable heterogeneous catalyst for C-2 arylation of indoles with arylboronic acids
Bhattacharjee P, et al.
New. J. Chem., 44, 7675-7682 (2020)
Commercial Pd/C-catalyzed N-methylation of nitroarenes and amines using methanol as both C1 and H2 source
Goyal V, et al.
The Journal of Organic Chemistry, 84, 15389-15398 (2019)
Palladium on Carbon
Anthony OK and Ichiro S
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Pd/C-catalyzed transfer hydrogenation of aromatic nitro compounds using methanol as a hydrogen source
Goyal V, et al.
Journal of the Indian Chemical Society, 98, 100014-100014 (2021)
Pd/C-catalyzed facile synthesis of primary aromatic amides by aminocarbonylation of aryl iodides using ammonia surrogates
Mane RS and Bhanage BM
Royal Society of Chemistry Advances, 5, 76122-76127 (2015)

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