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Safety Information

301949

Sigma-Aldrich

(1R)-(−)-10-Camphorsulfonyl chloride

97%

Synonym(s):

(−)-Camphor-10-sulfonyl chloride, (1R)-Camphor-10-sulfonic acid chloride

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About This Item

Empirical Formula (Hill Notation):
C10H15ClO3S
CAS Number:
39262-22-1
Molecular Weight:
250.74
Beilstein:
3205975
MDL number:
MFCD00064155
UNSPSC Code:
12352115
PubChem Substance ID:
24858220
NACRES:
NA.22

Assay

97%

form

solid

optical activity

[α]18/D −33°, c = 3 in chloroform

mp

66-68 °C (lit.)

SMILES string

[H][C@]12CC[C@](CS(Cl)(=O)=O)(C(=O)C1)C2(C)C

InChI

1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m0/s1

InChI key

BGABKEVTHIJBIW-XVKPBYJWSA-N

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Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

301949-25G:
301949-VAR:
301949-5G:
301949-BULK:

Certificates of Analysis (COA)

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T Jira et al.
Die Pharmazie, 48(11), 829-833 (1993-11-01)
Investigations on direct separation by RP-HPLC of selected enantiomeric beta-adrenergic active agents are described. R- and S-1-phenylethylisocyanate (PEIC) as well as (1S)-(+)-campher-10-sulfonylchloride (CSC) are used for the derivatization of the compounds. Correlations between chromatographic data and various influences (pH, temperature

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