Skip to Content
Merck
All Photos(1)

Key Documents

Safety Information

249998

Sigma-Aldrich

Titanium(III) chloride solution

~10 wt. % in 20-30 wt. % hydrochloric acid

Synonym(s):

Titanium trichloride

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
TiCl3
CAS Number:
Molecular Weight:
154.23
MDL number:
UNSPSC Code:
12352301
PubChem Substance ID:

reaction suitability

reagent type: catalyst
core: titanium

concentration

~10 wt. % in 20-30 wt. % hydrochloric acid

density

1.192 g/mL at 25 °C

SMILES string

Cl[Ti](Cl)Cl

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

Looking for similar products? Visit Product Comparison Guide

Application

Catalyst for:
Hydrogen desorption properties[1]
Nitrogen-nitrogen reductive bond cleavage[2]

Reagent for:
Photocatalyst synthesis[3]
Preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeleton[4]

Other Notes

Exact concentration stated on label

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

249998-VAR:
249998-25ML:4548173124612
249998-500ML:4548173124629
249998-BULK:


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

S. Isobe, et al.,
Applied Physics Letters, 99 (2011)
Shuxi Dai et al.
Nanoscale research letters, 5(11), 1829-1835 (2010-12-03)
Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy
D. Meroni, et al
Catalysis Today, 161, 169-174 (2011)
Jun-ichi Matsuo et al.
Organic letters, 12(14), 3266-3268 (2010-06-24)
N-p-Toluenesulfonyl (Ts) aldimines reacted with 3-ethoxycyclobutanones by catalysis of titanium(IV) chloride to afford 2,3-di- or 2,3,3-trisubstituted N-Ts-2,3-dihydro-4-pyridones. Synthesis of (+/-)-bremazocine was efficiently accomplished by using this method.
Palaniappan Kulanthaivel et al.
Drug metabolism and disposition: the biological fate of chemicals, 32(9), 966-972 (2004-08-21)
Phase I oxidative metabolism of nitrogen-containing drug molecules to their corresponding N-oxides is a common occurrence. There are instances where liquid chromatography/tandem mass spectometry techniques are inadequate to distinguish this pathway from other oxidation processes, including C-hydroxylations and other heteroatom

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service