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Safety Information

180033

Sigma-Aldrich

4-Methoxy-N-methylaniline

98%

Synonym(s):

N-Methyl-p-anisidine

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About This Item

Linear Formula:
CH3OC6H4NHCH3
CAS Number:
5961-59-1
Molecular Weight:
137.18
Beilstein:
774640
EC Number:
227-735-1
MDL number:
MFCD00008399
UNSPSC Code:
12352100
PubChem Substance ID:
24850845
NACRES:
NA.22

Assay

98%

form

solid

bp

135-136 °C/19 mmHg (lit.)

mp

33-36 °C (lit.)

SMILES string

CNc1ccc(OC)cc1

InChI

1S/C8H11NO/c1-9-7-3-5-8(10-2)6-4-7/h3-6,9H,1-2H3

InChI key

JFXDIXYFXDOZIT-UHFFFAOYSA-N

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General description

The allylation of N-methyl-p-anisidine by quaternary allylammonium cation was studied.

Application

4-Methoxy-N-methylaniline (N-Methyl-p-anisidine) was used to study the additive effects of amines.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

180033-VAR:
180033-BULK:
180033-5G:
180033-10G:
180033-1G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The additive effects of amines were realized in the asymmetric hydrogenation of 2-phenylquinoxaline, and its derivatives, catalyzed by chiral cationic dinuclear triply halide-bridged iridium complexes [{Ir(H)[diphosphine]}(2)(μ-X)(3)]X (diphosphine = (S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl [(S)-BINAP], (S)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole [(S)-SEGPHOS], (S)-5,5'-bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole [(S)-DIFLUORPHOS]; X = Cl, Br, I) to

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