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125075

Sigma-Aldrich

2-Chloro-4-methylaniline

98%

Synonym(s):

2-Chloro-p-toluidine, 4-Amino-3-chlorotoluene

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About This Item

Linear Formula:
ClC6H3(CH3)NH2
CAS Number:
Molecular Weight:
141.60
Beilstein:
774514
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

liquid

refractive index

n20/D 1.575 (lit.)

bp

223-225 °C (lit.)

mp

7 °C (lit.)

solubility

methanol: soluble

density

1.151 g/mL at 25 °C (lit.)

SMILES string

Cc1ccc(N)c(Cl)c1

InChI

1S/C7H8ClN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3

InChI key

XGYLSRFSXKAYCR-UHFFFAOYSA-N

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Application

2-Chloro-4-methylaniline was used in determination of aniline derivatives in environmental water samples using on-line combination of supported liquid membrane extraction and liquid chromatography. It was also used in determination of amines in environmental water samples by gas chromatography–mass spectrometry.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

210.2 °F - closed cup

Flash Point(C)

99 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

125075-25G:
125075-BULK:
125075-VAR:
125075-5G:


Certificates of Analysis (COA)

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Fully automated on-line supported liquid membrane-liquid chromatographic determination of aniline derivates in environmental waters.
Norberg J, et al.
Chromatographia, 46(9-10), 483-488 (1997)
Miguel del Nogal Sánchez et al.
Analytical and bioanalytical chemistry, 404(6-7), 2007-2015 (2012-08-14)
We report a sensitive method for the determination of 15 aromatic amines in environmental water samples. They have been included in the list of priority pollutants in surface water by the European Union. The method is based on analyte enrichment

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