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Safety Information

110019

Sigma-Aldrich

Diisopropylamine

99%

Synonym(s):

DIPA

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About This Item

Linear Formula:
(CH3)2CHNHCH(CH3)2
CAS Number:
108-18-9
Molecular Weight:
101.19
Beilstein:
605284
EC Number:
203-558-5
MDL number:
MFCD00008862
UNSPSC Code:
12352100
PubChem Substance ID:
329749267

vapor density

3.5 (vs air)

vapor pressure

50 mmHg ( 20 °C)

Assay

99%

form

liquid

autoignition temp.

599 °F

expl. lim.

8.5 %

availability

available only in EU

refractive index

n20/D 1.392 (lit.)

bp

84 °C (lit.)

mp

−61 °C (lit.)

solubility

water: soluble 110 g/L at 25 °C

density

0.722 g/mL at 25 °C (lit.)

SMILES string

CC(C)NC(C)C

InChI

1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3

InChI key

UAOMVDZJSHZZME-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

7.8 °F - closed cup

Flash Point(C)

-13.45 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

110019-18L:
110019-VAR:
110019-2.5L:
110019-BULK:
110019-100ML:
110019-500ML:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Reaction of amines and acid catalysts. IV. Kinetics and mechanism of olefin formation from triethylamine and diisopropylamine on ?-alumina.
Hogan P and Pasek J.
Collection of Czechoslovak Chemical Communications, 38(5), 1513-1521 (1973)
Synthesis of high carbon materials from acetylenic precursors. Preparation of aromatic monomers bearing multiple ethynyl groups.
Neenan TX and Whitesides GM.
The Journal of Organic Chemistry, 53(11), 2489-2496 (1988)
Songping Liao et al.
Journal of the American Chemical Society, 125(49), 15114-15127 (2003-12-05)
Lithium diisopropylamide-mediated lithiations of N-alkyl ketimines derived from cyclohexanones reveal that simple substitutions on the N-alkyl side chain and the 2-position of the cyclohexyl moiety afford a 60,000-fold range of rates. Detailed rate studies implicate monosolvated monomers at the rate-limiting
Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.
David R Armstrong et al.
Angewandte Chemie (International ed. in English), 49(18), 3185-3188 (2010-03-31)
Kanwal Jit Singh et al.
Journal of the American Chemical Society, 128(42), 13753-13760 (2006-10-19)
Structural and mechanistic studies of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates are described. Substituents at the meta position of the arene (H, OMe, F) and the dialkylamino moiety of the carbamate (Me(2)N, Et(2)N, and i-Pr(2)N) markedly
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