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About This Item
Empirical Formula (Hill Notation):
C99H79Cl2N3Pd
Molecular Weight:
1488.03
UNSPSC Code:
12352200
NACRES:
NA.22
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Quality Level
Assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
Pd(IPr#)(AN)Cl2 is a Pd-catalyst that can be used in a broad range of reactions, including cross-coupling, C-H functionalization, electrophilic additions. NHC-Pd-aniline complexes of this type have many advantages, including higher reactivity in cross-coupling reactions than similar complexes using cinnamyl and pyridine throw-away ligands and simple reaction tunability through substituion of aniline ligand.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
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Qun Zhao et al.
Chemical science, 12(31), 10583-10589 (2021-08-28)
IPr (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) represents the most important NHC (NHC = N-heterocyclic carbene) ligand throughout the field of homogeneous catalysis. Herein, we report the synthesis, catalytic activity, and full structural and electronic characterization of novel, sterically-bulky, easily-accessible NHC ligands based
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