- Structural characterization of the first hydroxo-bridged plutonium compound, (PuO(2))(2)(IO(3))(mu(2)-OH)(3).
Structural characterization of the first hydroxo-bridged plutonium compound, (PuO(2))(2)(IO(3))(mu(2)-OH)(3).
Inorganic chemistry (2005-07-19)
Amanda C Bean, Kent Abney, Brian L Scott, Wolfgang Runde
PMID16022517
ABSTRACT
The hydrothermal reaction of a (239)Pu(IV) stock solution in the presence of iodic acid and 1 M KOH produces reddish-brown single crystals of (PuO(2))(2)(IO(3))(OH)(3). The structure consists of two-dimensional layers forming in the ac plane and is the first single-crystal structure of plutonium(VI) connected through hydroxide anions. The additional linkage of plutonium centers is completed through iodate ligands.