708275

1,3-Bis-(2,6-diisopropylphenyl)-[1,3,2]diazaphospholidine 2-oxide

97%

• Sinonimo/i: 1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3,2-diazaphospholidine 2-oxide
• Formula empirica (notazione di Hill): C₂₆H₃₉N₂OP
• Numero CAS: 854929-36-5
• Peso molecolare: 426.57
• Numero MDL: MFCD14708169
• Codice UNSPSC: 12352005
• ID PubChem: 329762783

Proprietà

• Saggio: 97%
• Stato: solid
• Impiego in reazioni chimiche: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• Punto di fusione: 205-210 °C
• Gruppo funzionale: phosphine
• Stringa SMILE: CC(C)c1cccc(C(C)C)c1N2CCN(c3c(cccc3C(C)C)C(C)C)[PH]2=O
• InChI: 1S/C26H39N2OP/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28(30(27)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-14,17-20,30H,15-16H2,1-8H3; SQYNIVDXVZPMLW-UHFFFAOYSA-N

Descrizione

Applicazioni

Ligand used with ruthenium for dehydrative direct arylation of arenes with phenols[1]

Reactnat for synthesis of air-stable palladium HASPO complexes

Catalyst for:

• Dehydrative direct arylations of arenes
• Aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 2
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)