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365203

Sigma-Aldrich

Lithium p-toluenesulfinate

98%

Synonym(s):

p-Toluenesulfinic acid lithium salt

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About This Item

Linear Formula:
CH3C6H4SO2Li
CAS Number:
16844-27-2
Molecular Weight:
162.14
Beilstein:
4163977
EC Number:
240-867-4
MDL number:
MFCD00035601
UNSPSC Code:
12352100
PubChem Substance ID:
24862493

Assay

98%

impurities

≤2% Li2CO3

SMILES string

[Li+].Cc1ccc(cc1)S([O-])=O

InChI

1S/C7H8O2S.Li/c1-6-2-4-7(5-3-6)10(8)9;/h2-5H,1H3,(H,8,9);/q;+1/p-1

InChI key

MSUZXYWQEDRGFN-UHFFFAOYSA-M

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Application

Lithium p-toluenesulfinate may be used in the preparation of 2-oxo-1,3-diphenyl-1,2-dihydroquinoline-4-carbonitrile.[1] It may be used in the preparation of highly fluorescent compound, 3-amino-6-methoxy-4-p-tolylsulfonylquinolone.[2]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBB4201
BCBB4201V
016823/1
05207KH
11005LE

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4-Cyano-6, 7-dimethoxycarbostyrils with Solvent-and pH-Independent High Fluorescence Quantum Yields and Emission Maxima.
Ahvale AB, et al.
European Journal of Organic Chemistry, 3, 563-571 (2008)
Month 2013 6-Methoxy-2-oxo-1, 2-dihydroquinoline-3, 4-dicarbonitriles, A Red Compound Class with Solvent and pH Independent Green Fluorescence Maxima.
Enoua GC, et al.
Journal of Heterocyclic Chemistry, 51, 492-501 (2014)
Xiaoxiang Zhang et al.
The Journal of organic chemistry, 75(18), 6290-6293 (2010-08-28)
A general and efficient method to prepare 2,4-di- and trisubstituted thiazoles via p-TsOH·H(2)O-catalyzed cyclization of trisubstituted propargylic alcohols with thioamides is described. The reaction was accomplished in moderate to excellent product yields under mild conditions that did not require the
K Eulitz et al.
Lipids, 34(8), 873-877 (1999-10-21)
Conjugated linoleic acid (CLA) mixtures were isomerized with p-toluenesulfinic acid or I2 catalyst. The resultant mixtures of the eight cis/trans geometric isomers of 8,10-, 9,11-, 10,12-, and 11,13-octadecadienoic (18:2) acid methyl esters were separated by silver ion-high-performance liquid chromatography (Ag+-HPLC)
C Bernofsky et al.
Free radical research communications, 9(3-6), 303-315 (1990-01-01)
Adenosine and its nucleotides react with hypochlorite to form unstable products that have been identified as the N6 chloramine derivatives. These chloramines spontaneously oligomerize, form stable adducts with proteins and nucleic acids, and are converted with loss of chlorine to
View All Related Papers

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