703559
Lanthanum(III) chloride bis(lithium chloride) complex solution
0.6 M in THF
Synonym(s):
Lanthanum trichloride lithium chloride complex
About This Item
Recommended Products
form
liquid
Quality Level
reaction suitability
reagent type: catalyst
core: lanthanum
concentration
0.6 M in THF
16 % (w/w)
density
1.05 g/mL at 25 °C
SMILES string
[Li]Cl.[Li]Cl.Cl[La](Cl)Cl
InChI
1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5
InChI key
YSKOYVQYUJUXCN-UHFFFAOYSA-I
Application
- Mediates Grignard additions
- Reagent for metal exchange reactions
- Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines
Legal Information
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
62.6 °F
Flash Point(C)
17 °C
Personal Protective Equipment
Certificates of Analysis (COA)
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Grignard reagent's 1,2-addition to ketones is powerful but selective issues often arise from competitive alpha-deprotonation.
Grignard reagent's 1,2-addition to ketones is powerful but selective issues often arise from competitive alpha-deprotonation.
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