- The synthesis of 2-deoxy-α-D-glycosides from D-glycals catalyzed by TMSI and PPh3.
The synthesis of 2-deoxy-α-D-glycosides from D-glycals catalyzed by TMSI and PPh3.
Carbohydrate research (2012-08-03)
Xi-Kai Cui, Ming Zhong, Xiang-Bao Meng, Zhong-Jun Li
PMID22854184
ABSTRACT
2-Deoxyglycosides were synthesized in high α-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh(3). The acid labile isopropylidene group is tolerated under this condition.
MATERIALS