24260
Chlorodicyclohexylborane solution
purum, ~1 M in hexane
Synonym(s):
Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
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About This Item
Linear Formula:
(C6H11)2BCl
CAS Number:
Molecular Weight:
212.57
Beilstein:
3233942
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
grade
purum
reaction suitability
reagent type: reductant
concentration
~1 M in hexane
density
0.74 g/mL at 20 °C
SMILES string
ClB(C1CCCCC1)C2CCCCC2
InChI
1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key
PBBOKJIYEZCTEH-UHFFFAOYSA-N
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Application
Reactant for:
- Aldol addition reactions
- Mukaiyama aldol addition
- Microwave assisted ring closing metathesis reactions
- C-alkylation of aromatic aldimines
- Reversible ketone-ketone aldol reactions
- Syn- and anti-stereoselective aldol reaction hexenone with aldehydes
Other Notes
Ideal reagent for the generation of E-enol borinates from ketones in high stereoselectivity
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Find documentation for the products that you have recently purchased in the Document Library.
K. Ganesan et al.
The Journal of Organic Chemistry, 58, 7162-7162 (1993)
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