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  • Adsorptive removal of bisphenol-A from water with a metal-organic framework, a porous chromium-benzenedicarboxylate.

Adsorptive removal of bisphenol-A from water with a metal-organic framework, a porous chromium-benzenedicarboxylate.

Journal of nanoscience and nanotechnology (2013-06-15)
Eun Young Park, Zubair Hasan, Nazmul Abedin Khan, Sung Hwa Jhung
ABSTRACT

Adsorptive removal of bisphenol-A (BPA) using a MOF, Cr-benzenedicarboxylate (MIL-53), has been studied to understand the applicability of MOFs for the removal of hazardous endocrine disturbing chemicals from water. MIL-53 shows very fast adsorption in an hour and the adsorption capacity of MIL-53 is higher than that of activated carbon. Importantly, the adsorption of BPA over MIL-53 is very favorable especially at very low concentrations of BPA. Therefore, MOFs such as MIL-53 can be one of adsorbents that may be used in the adsorptive removal of BPA from contaminated water.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Chromium, chips, thickness ~2 mm, 99.5%
Sigma-Aldrich
Chromium, powder, ≥99% trace metals basis, <45 μm
Sigma-Aldrich
Chromium, powder, 99.5%, −100 mesh
Sigma-Aldrich
Chromium, chips, 99.995% trace metals basis
Sigma-Aldrich
Bisphenol A, 97%
Supelco
Benzene, analytical standard
Supelco
Benzene solution, certified reference material, TraceCERT®, 200 μg/mL in methanol
Sigma-Aldrich
Benzene, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Benzene, ACS reagent, ≥99.0%
Supelco
Bisphenol A, ≥99%
Sigma-Aldrich
Benzene, anhydrous, 99.8%
Supelco
Benzene, Pharmaceutical Secondary Standard; Certified Reference Material
Sigma-Aldrich
Benzene, puriss. p.a., reag. Ph. Eur., ≥99.7%