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Merck

Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.

Chemical communications (Cambridge, England) (2002-07-19)
Steven V Ley, Chandrashekar Ramarao, Richard S Gordon, Andrew B Holmes, Angus J Morrison, Ian F McConvey, Ian M Shirley, Stephen C Smith, Martin D Smith
RESUMEN

Palladium(II) acetate microencapsulated in polyurea (MC-[Pd]) is an economical and versatile heterogeneous catalyst for a range of phosphine-free cross-coupling reactions in both conventional solvents and supercritical carbon dioxide (scCO2); the catalyst can be recovered by a simple filtration and recycled up to four times.

MATERIALES
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Sigma-Aldrich
[Pd(OAc)2]3, ≥99.9% trace metals basis
Sigma-Aldrich
Pd EnCat® 30, extent of labeling: 0.4 mmol/g Pd loading
Sigma-Aldrich
Pd EnCat® 40, extent of labeling: 0.4 mmol/g Pd loading