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  • Synthesis and catalytic properties of mesoporous, bifunctional, gallium-niobium mixed oxides.

Synthesis and catalytic properties of mesoporous, bifunctional, gallium-niobium mixed oxides.

Chemical communications (Cambridge, England) (2010-08-18)
Chinmay A Deshmane, Jacek B Jasinski, Paul Ratnasamy, Moises A Carreon
ABSTRACT

Thermally stable mesoporous Ga-Nb mixed oxides, active in both acid-catalysed and redox reactions have been synthesized via self-assembly hydrothermal assisted approach. Methyl oleate, a major component of biodiesels, undergoes double bond and skeletal isomerisation as well as dehydrogenation over these novel mesophases.

MATERIALS
Product Number
Brand
Product Description

Supelco
Methyl elaidate, analytical standard
Sigma-Aldrich
Methyl elaidate, ≥99% (capillary GC)
Sigma-Aldrich
Methyl oleate, technical grade, 70%
Sigma-Aldrich
Methyl oleate, 99%
Supelco
Methyl oleate, analytical standard