- A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion.
A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion.
Dalton transactions (Cambridge, England : 2003) (2009-01-06)
Masahiko Maekawa, Atsuhiro Nabei, Toshi Tominaga, Kunihisa Sugimoto, Toshie Minematsu, Takashi Okubo, Takayoshi Kuroda-Sowa, Megumu Munakata, Susumu Kitagawa
PMID19122896
摘要
Three novel Cu(I)-C2H4 adducts bearing 4-(2-pyridyl)pyrimidine were self-assembled, and the roles of anion and solvent were proved in the formation process.