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Merck

M3205

Sigma-Aldrich

2-巯基苯并咪唑

98%

别名:

1,3-二氢-2 H -苯并咪唑-2-硫酮, 2-苯并咪唑硫醇

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About This Item

经验公式(希尔记法):
C7H6N2S
CAS号:
分子量:
150.20
Beilstein:
119867
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

mp

300-304 °C (lit.)

SMILES 字串

S=C1Nc2ccccc2N1

InChI

1S/C7H6N2S/c10-7-8-5-3-1-2-4-6(5)9-7/h1-4H,(H2,8,9,10)

InChI 密鑰

YHMYGUUIMTVXNW-UHFFFAOYSA-N

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相关类别

一般說明

2-巯基苯并咪唑能降低金属腐蚀速度,是良好的缓蚀剂。

應用

2-巯基苯并咪唑用于:
  • 与芳香酮反应制备2-苯并咪唑基硫代苯乙酮,这是合成噻唑并[3,2-a]苯并咪唑的关键中间体。
  • 合成 S-芳基化2-巯基苯并咪唑,合成物由与CuI和1,10-菲咯啉形成的取代芳基碘化物进行 S-芳基化反应得到。

象形圖

Skull and crossbonesHealth hazard

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 2

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Kazue Sakemi et al.
Archives of toxicology, 76(12), 682-691 (2002-11-27)
2-Mercaptobenzimidazole (MBI), a rubber antioxidant, is known to exhibit potent thyroid toxicity in rats, whereas its methylated derivatives are much less toxic. To characterize this methyl-substituent effect on the thyroid toxicity of MBI, comparative toxicokinetic analyses have been conducted in
Yuqin Li et al.
Colloids and surfaces. B, Biointerfaces, 104, 311-317 (2013-01-22)
The interaction of 2-mercaptobenzimidazole (MBI) with human serum albumin (HSA) was studied in vitro by equilibrium dialysis under normal physiological conditions. This study used fluorescence, ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared (FT-IR), circular dichroism (CD) and Raman spectroscopy, atomic force
S-arylation of mercaptobenzimidazoles using Cu (I) catalysts-experimental and theoretical observations
Sekar R, et al.
Tetrahedron Letters, 52(26), 3347-3352 (2011)
D M Manohar et al.
Water research, 36(6), 1609-1619 (2002-05-09)
The 2-mercaptobenzimidazole loaded natural clay was prepared for the removal of Hg(II) from aqueous media. Adsorption of the metal ions from aqueous solution as a function of solution concentration, agitation time, pH, temperature, ionic strength, particle size of the adsorbent
Edésio F C Alcântara et al.
Journal of colloid and interface science, 311(1), 1-7 (2007-04-10)
The compound 2-mercaptobenzimidazole (MBI) was attached onto a silica gel surface by homogeneous and heterogeneous routes. Both silica modification methodologies resulted in similar products, named SiM(hom) and SiM(het), respectively. These materials were characterized by surface area, infrared, thermogravimetry, and 13C

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