935638

三(三甲基硅基)磷

≥99.0%, anhydrous, battery grade

• 别名: 磷酸三(三甲基硅基)酯
• 线性分子式: [(CH₃)₃SiO]₃P(O)
• CAS号: 10497-05-9
• 分子量: 314.54
• Beilstein: 1794624
• MDL號碼: MFCD00008267
• 分類程式碼代碼: 12352005

属性

• 等級: battery grade
• 品質等級: 100
• 描述: Application: Battery manufacturing
• 化驗: ≥99.0%
• 形狀: (colorless liquid)
• 環保替代產品特色: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 雜質: ppm H2O≤500; ≤500 ppm H₂O
• 折射率: n20/D 1.409 (lit.)
• bp: 228-229 °C/720 mmHg (lit.); 228-229 °C
• mp: 3-4 °C (lit.); 3-4 °C
• 密度: 0.945 g/mL at 25 °C (lit.)
• 應用: battery manufacturing
• 環保替代類別: Enabling
• SMILES 字串: C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C
• InChI: 1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
• InChI 密鑰: QJMMCGKXBZVAEI-UHFFFAOYSA-N

说明

一般說明

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

應用

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF₆-based electrolytes at elevated temperatures.TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

安全信息

• 象形圖: GHS02,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H315,H319,H335
• 防範說明: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 2
• 閃點（°F）: 55.4 °F - closed cup
• 閃點（°C）: 13 °C - closed cup