790885

(R)-3,3′-Dibromo-1,1′-binaphthyl-2,2′-disulfonimide toluene complex

97%

• 别名: (11bR)-2,6-Dibromodinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine- 3,3,5,5-tetraoxide
• 经验公式（希尔记法）: (C₂₀H₁₁Br₂NO₄S₂)₂ · C₆H₅CH₃
• 分子量: 1198.63
• MDL號碼: MFCD28016339
• 分類程式碼代碼: 12352005
• PubChem物質ID: 329768247
• NACRES: NA.22

属性

• 化驗: 97%
• 形狀: solid
• 反應適用性: reaction type: Aldol Reaction; reaction type: Allylation; reaction type: Carbonyl/Imine Addition; reaction type: Friedel-Crafts Alkylation
• mp: 306-310 °C
• SMILES 字串: CC1=CC=CC=C1.BrC2=CC(C=CC=C3)=C3C(C4=C(C=CC=C5)C5=CC(Br)=C4S6(=O)=O)=C2S(N6)(=O)=O.BrC7=CC(C=CC=C8)=C8C(C9=C(C=CC=C%10)C%10=CC(Br)=C9S%11(=O)=O)=C7S(N%11)(=O)=O
• InChI: 1S/2C20H11Br2NO4S2.C7H8/c2*21-15-9-11-5-1-3-7-13(11)17-18-14-8-4-2-6-12(14)10-16(22)20(18)29(26,27)23-28(24,25)19(15)17;1-7-5-3-2-4-6-7/h2*1-10,23H;2-6H,1H3
• InChI 密鑰: WQYRPPIFPJBANM-UHFFFAOYSA-N

说明

應用

Chiral Bronsted acid amenable to modification at the 3 and 3′ positions.

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

Chiral Sulfonimide as a Brønsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines

A href="http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201300956/abstract" target="_blank">Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable