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Merck

543306

Sigma-Aldrich

2,7-二叔丁基芴

98%

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About This Item

经验公式(希尔记法):
C21H26
CAS号:
分子量:
278.43
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

mp

121-124 °C (lit.)

SMILES 字串

CC(C)(C)c1ccc-2c(Cc3cc(ccc-23)C(C)(C)C)c1

InChI

1S/C21H26/c1-20(2,3)16-7-9-18-14(12-16)11-15-13-17(21(4,5)6)8-10-19(15)18/h7-10,12-13H,11H2,1-6H3

InChI 密鑰

DFZYPLLGAQIQTD-UHFFFAOYSA-N

一般說明

2,7-Di-tert-butylfluorene can be synthesized by reacting fluorene, CS2 and FeCl3 and 2-chloro-2-methylpropane. It can also be obtained by reacting fluorene with tert-butyl chloride in the presence of FeCl3.

應用

2,7-Di-tert-butylfluorene may be used in the preparation of:
  • 2,7-di-tert-butyl-9-fluorenylmethanol
  • 2,7-di-tert-butyl-9-[ [(p-chlorophenyl)amino]methylene]-fluorene
  • dihydrocyclohepta[def]fluorene
  • new group 4 metal complexes containing aminofluorenyl ligands

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Miller SA and Bercaw JE.
Organometallics, 19, 5608-5608 (2000)
Synthesis and Properties of Kinetically Stabilized Cyclohepta [def] fluorene Derivatives.
Grieser, UD and Hafner K.
Chemische Berichte, 127(11), 2307-2314 (1994)
Investigation of the reaction between amino acids or amino acid esters and 9-formylfluorene and its equivalents. Possible utility of the derived enamines as amino group protectants.
Carpino LA, et al.
The Journal of Organic Chemistry, 54(18), 4302-4313 (1989)
Fmoc: a more soluble analogue of the 9-fluorenylmethoxycarbonyl protecting group.
K D Stigers et al.
The Journal of organic chemistry, 65(12), 3858-3860 (2000-06-24)

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