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  • [Degradation of dimethyl phthalate (DMP) in aqueous solution by UV/Si-FeOOH/H2O2].

[Degradation of dimethyl phthalate (DMP) in aqueous solution by UV/Si-FeOOH/H2O2].

Huan jing ke xue= Huanjing kexue (2010-11-16)
Kun-Lin Li, Wu-Qiang Chen, Xiao-Ting Li, Bao-Ling Yuan
ABSTRACT

In this study the new catalyst Si-FeOOH was synthesized by adding Si to the traditional FeOOH and the mechanic strength of this new catalyst could be enhanced greatly. The photo-degradation of dimethyl phthalate (DMP) by UV/Si-FeOOH/H2O2 was investigated. The new catalyst Si-FeOOH was amorphous structure with high surface area and low soluble iron by XRD, IR and SEM. The efficiency of DMP degradation by UV/Si-FeOOH/H2O2 could reach 97% after 30 min reaction time at pH 5, 0.5 g/L dosage of Si-FeOOH, and 2.0 mmol/L of H2O2 under 125W UV365 irradiation. DMP could be degraded effectively by synergistic effect of UV, Si-FeOOH and H2O2. The Si-FeOOH photocatalyst can be very easily recovered and its catalytic activity also remained after several rounds of reaction.

MATERIALS
Product Number
Brand
Product Description

Supelco
Dimethyl phthalate, PESTANAL®, analytical standard
Sigma-Aldrich
Dimethyl phthalate, ≥99%
Sigma-Aldrich
Dimethyl phthalate, ≥99%
Sigma-Aldrich
Dimethyl phthalate, SAJ special grade, ≥99.0%