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Merck

471313

Sigma-Aldrich

Tributylamine

≥98.5%

Sinónimos:

Tri-n-butylamine

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About This Item

Fórmula lineal:
[CH3(CH2)3]3N
Número de CAS:
Peso molecular:
185.35
Beilstein/REAXYS Number:
1698872
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

vapor density

6.38 (vs air)

Quality Level

vapor pressure

0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)

assay

≥98.5%

form

liquid

autoignition temp.

410 °F

expl. lim.

6 %

refractive index

n20/D 1.428 (lit.)

pH

10.2 (25 °C, 0.1 g/L)

bp

216 °C (lit.)

mp

−70 °C (lit.)

density

0.778 g/mL at 25 °C (lit.)

SMILES string

CCCCN(CCCC)CCCC

InChI

1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI key

IMFACGCPASFAPR-UHFFFAOYSA-N

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General description

Tributylamine (TBA) is a tertiary amine used as strong base anion (SBA) exchange resin. TBA can also be used as a corrosion inhibitor for mild steel in HCl solution. Additionally, it can be used as a base solvent in various organic synthesis.

Application

Tributylamine may be used as:
  • An extraction solvent with CHCA (α-cyano-4-hydroxycinnamic acid) for the selective phospholipids (PLs) extraction from EVOO (extra virgin olive oil) and HO (hazelnut oil).
  • A hydroxylating agent in the synthesis of spinel nickel ferrites (NiFe2O4) nanoparticles (NPs).

Features and Benefits

In various co-precipitation methods, tributylamine is used as a hydroxylating agent instead of NaOH and NH4OH since it causes a uniform rise in pH which prevents local supersaturation and promotes homogeneous nucleation throughout the solution.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Skin Irrit. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 1

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup


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This study presents a systematic investigation of factors influencing the chromatographic separation of diastereomers of phosphorothioated pentameric oligonucleotides as model solutes. Separation was carried out under ion-pairing conditions using an XBridge C18 column. For oligonucleotides with a single sulfur substitution
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The analytical performance of an atmospheric pressure sampling, multiple-channel, high-throughput mass spectrometer was investigated using samples of a variety of types. The instrument, based on an array of cylindrical ion traps, was built with four independent channels and here is
N Ghoneim
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(3), 483-489 (2001-04-13)
The influence of temperature on the efficiency of fluorescence of the encounter complex (A- ...D+)* in intermolecular electron transfer starting from neutral precursors has been studied. In contrast to what is generally assumed, fluorescence emission of the exciplexes is found
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The study of the solubility of unstructured proteins (alpha s1-, beta-, and kappa-casein) and well-structured globulin (beta-lactoglobulin) in low water binary solvent systems demonstrated the crucial importance of solvent polarity and neutralization of protein polar functions on the final outcome
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Journal of chromatography. A, 1217(4), 479-488 (2009-12-17)
Reverse-phase ion-pair high performance liquid chromatography (RPIP-HPLC) and ultra-performance liquid chromatography (RPIP-UPLC) are increasingly popular chromatographic techniques for the separation of organic compounds. However, the fine details of the RPIP separation mechanism are still being debated. Many factors including type

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