Saltar al contenido
Merck
Todas las fotos(1)

Key Documents

View All Documentation

797537

Sigma-Aldrich

PhenoFluor™ Mix

Sinónimos:

N,N?′-1,3-bis(2,6-diisopropylphenyl)chloroimidazolium chloride and CsF mixture (1:2)

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(1)

About This Item

UNSPSC Code:
12352101
PubChem Substance ID:
329768607
NACRES:
NA.22

form

powder

Quality Level

100

mp

228.65 °C

SMILES string

[Cs]F.Cl[C+]1=[N](C2=C(C(C)C)C=CC=C2C(C)C)C=CN1C3=C(C(C)C)C=CC=C3C(C)C.[Cl-]

InChI

1S/C27H36ClN2.ClH.Cs.FH/c1-17(2)21-11-9-12-22(18(3)4)25(21)29-15-16-30(27(29)28)26-23(19(5)6)13-10-14-24(26)20(7)8;;;/h9-20H,1-8H3;1H;;1H/q+1;;+1;/p-2

Inchi Key

AHNDOFVAHQKSBA-UHFFFAOYSA-L

General description

PhenoFluor™ Mix is a mixture of N,N′-1,3-bis(2,6-diisopropylphenyl)chloroimidazolium chloride and CsF in 1:2 weight ratio.

Application

PhenoFluor™ Mix is a benchtop stable alternative to PhenoFluor™, which is a reagent for the deoxyfluorination of phenols, including electron-deficient, electron-rich, and heterocyclic phenols. Deoxyfluorination with PhenoFluor™ Mix is operationally simple and scalable.

Other Notes

Mix well, before use. Material can separate when not in use.

Legal Information

PhenoFluor is a trademark of SciFluor Life Sciences, LLC
PhenoFluor is a trademark of SciFluor Life Sciences, LLC

related product

Referencia del producto
Descripción
Precios

900456

AlkylFluor

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Kidney,Adrenal gland, Respiratory system

supp_hazards

EUH032

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

PhenoFluorMix: practical chemoselective deoxyfluorination of phenols.
Fujimoto T and Ritter T
Organic Letters, 17(3), 544-547 (2015)
Facile C-F Bond Formation through a Concerted Nucleophilic Aromatic Substitution Mediated by the PhenoFluor Reagent.
Neumann CN and Ritter T
Accounts of Chemical Research, 50(11), 2822-2833 (2017)
AlkylFluor: Deoxyfluorination of Alcohols.
Goldberg NW, et al.
Organic Letters, 18(23), 6102-6104 (2016)

Artículos

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

PhenoFluor™ Deoxyfluorination Solution

PhenoFluor™ enables one-step conversion of phenols to aryl fluorides, facilitating fluorination without pre-activation.

Contenido relacionado

Ritter Group – Professor Product Portal

The Ritter lab currently focuses on fluorination chemistry for late-stage functionalization of complex natural and unnatural products. PhenoFluor™ has been developed as a general reagent for the selective, predictable, direct deoxyfluorination of complex alcohols and phenols.

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico