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Merck

398195

Sigma-Aldrich

Lithium tert-butoxide solution

1.0 M in THF

Sinónimos:

tert-Butoxylithium, Lithium 2-methylpropan-2-olate, Lithium t-butoxide, Lithium tert-butylate, Lithium salt of tert-Butyl alcohol

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About This Item

Fórmula lineal:
(CH3)3COLi
Número de CAS:
Peso molecular:
80.05
Beilstein/REAXYS Number:
3620018
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

form

liquid

concentration

1.0 M in THF

bp

67 °C

density

0.888 g/mL at 25 °C

SMILES string

[Li+].CC(C)(C)[O-]

InChI

1S/C4H9O.Li/c1-4(2,3)5;/h1-3H3;/q-1;+1

Inchi Key

LZWQNOHZMQIFBX-UHFFFAOYSA-N

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Application

Lithium tert-butoxide solution is generally used as a strong base in organic synthesis.
It can be used:
  • For the synthesis of lithium modified silica nano-particles for conductive gel electrolytes.
  • As a catalyst for ring-opening polymerization of lactides.
  • As a lithium precursor for the synthesis of LiV3O8 nanoparticles by flame spray pyrolysis.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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