346977

(Triethylsilyl)acetylene

97%

• Sinónimos: Ethynyltriethylsilane
• Fórmula lineal: (C₂H₅)₃SiC≡CH
• Número de CAS: 1777-03-3
• Peso molecular: 140.30
• Beilstein/REAXYS Number: 1743814
• MDL number: MFCD00075373
• UNSPSC Code: 12352100
• PubChem Substance ID: 24861453
• NACRES: NA.22

Propiedades

• assay: 97%
• form: liquid
• refractive index: n20/D 1.433 (lit.)
• density: 0.783 g/mL at 25 °C (lit.)
• SMILES string: CC[Si](CC)(CC)C#C
• InChI: 1S/C8H16Si/c1-5-9(6-2,7-3)8-4/h1H,6-8H2,2-4H3
• InChI key: FWSPXZXVNVQHIF-UHFFFAOYSA-N

Descripción

General description

(Triethylsilyl)acetylene, a bulky trialkylsilyl-protected alkyne, undergoes Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to yield synthetically useful unsymmetrical diynes. Rhodium-catalyzed dimerization of (triethylsilyl)acetylene has been reported.

Application

(Triethylsilyl)acetylene may be used in the synthesis of triethylsilylethynyl anthradithiophenes, such as :

• 2,8-dimethyl-5,11-bis(triethylsilylethynyl)ADT (ADT= anthradithiophene)
• 2,8-diethyl-5,11-bis(triethylsilylethynyl)ADT
• 2,8-dipropyl-5,11-bis(triethylsilylethynyl)ADT

Información de seguridad

• pictograms: GHS02
• signalword: Danger
• hcodes: H225
• pcodes: P210 - P370 + P378 - P403 + P235
• Hazard Classifications: Flam. Liq. 2
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 62.6 °F - closed cup
• flash_point_c: 17 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter