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241431

Sigma-Aldrich

Tungsten hexacarbonyl

97%

Sinónimos:

Hexacarbonyltungsten, Tungsten carbonyl

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About This Item

Fórmula lineal:
W(CO)6
Número de CAS:
14040-11-0
Peso molecular:
351.90
EC Number:
237-880-2
MDL number:
MFCD00011462
UNSPSC Code:
12352103
PubChem Substance ID:
24854483
NACRES:
NA.23

vapor density

12.1 (vs air)

vapor pressure

1.2 mmHg ( 67 °C)

assay

97%

form

solid

reaction suitability

core: tungsten
reagent type: catalyst

impurities

<1% Mo

mp

150 °C (lit.)

density

2.65 g/mL at 25 °C (lit.)

SMILES string

[W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.W/c6*1-2;

InChI key

FQNHWXHRAUXLFU-UHFFFAOYSA-N

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Categorías relacionadas

Application

Precursor to a Fischer carbene complex which reduces Pd(II) to nanoparticulate Pd(0) that is catalytically active in Hiyama cross-coupling.
Tungsten hexacarbonyl, [W(CO)6] may be used as a precursor for the deposition of WO3-x films, which may be used as gas sensors for the detection of NO2.

Pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sigma-Aldrich

119318

Benzene-chromium(0) tricarbonyl

Hexacarbonylmolybdenum for synthesis

Sigma-Aldrich

8.00396

Hexacarbonylmolybdenum

Dipankar Srimani et al.
Organic letters, 9(18), 3639-3642 (2007-08-07)
An efficient synthesis of Pd nanoparticles in water has been developed using a Fischer carbene complex of tungsten as the reductant and PEG as the capping agent. The colloidal palladium (1 mol %) efficiently catalyzes Hiyama cross-coupling reactions performed in
Aerosol assisted chemical vapour deposition of WO 3 thin films from tungsten hexacarbonyl and their gas sensing properties.
Ashraf S, et al.
Journal of Materials Chemistry, 17.35, 3708-3713 (2007)
F Porrati et al.
Nanotechnology, 20(19), 195301-195301 (2009-05-08)
W-based granular metals have been prepared by electron-beam-induced deposition from the tungsten hexacarbonyl W(CO)(6) precursor. In situ electrical conductivity measurements have been performed to monitor the growth process and to investigate the behavior of the deposit under electron beam post-irradiation
S Martin et al.
The Journal of chemical physics, 134(3), 034304-034304 (2011-01-26)
We have studied the excitation and dissociation processes of the molecule W(CO)(6) in collisions with low kinetic energy (3 keV) protons, monocharged fluorine, and chlorine ions using double charge transfer spectroscopy. By analyzing the kinetic energy loss of the projectile
Seth M Dumbris et al.
The Journal of organic chemistry, 74(22), 8862-8865 (2009-10-30)
Hydantoins can be synthesized from the corresponding amino amides employing oxidative catalytic carbonylation using W(CO)(6) as the catalyst, I(2) as the oxidant, CO as the carbonyl source, and DBU as base. Secondary amides afford the hydantoins in good to excellent
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