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176435

Sigma-Aldrich

Silver trifluoromethanesulfonate

≥99%

Sinónimos:

Silver triflate, Trifluoromethanesulfonic acid silver salt

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About This Item

Fórmula lineal:
CF3SO3Ag
Número de CAS:
2923-28-6
Peso molecular:
256.94
Beilstein/REAXYS Number:
3598402
EC Number:
220-882-2
MDL number:
MFCD00013226
UNSPSC Code:
12161600
PubChem Substance ID:
24850578
NACRES:
NA.22

Quality Level

100

assay

≥99%

form

powder

reaction suitability

core: silver
reagent type: catalyst

mp

286 °C (lit.)

SMILES string

[Ag+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

QRUBYZBWAOOHSV-UHFFFAOYSA-M

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Application

Gold Catalysts — 21st Century ′Gold Rush′
Silver trifluoromethanesulfonate is a reactive triflating agent and source of soluble silver ions useful for formation of electrophilic onium species, and promotion of Friedel-Crafts, nucleophile alkene cyclization, and esterification reactions.
It can also be used:
  • To obtain olefins from secondary phosphates and thiophosphates.
  • As a reagent in the etherification of alcohols with primary alkyl halides under mild conditions.
  • To generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes.
  • As a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H315,H318

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Minoru Hayashi et al.
The Journal of organic chemistry, 71(24), 9248-9251 (2006-11-18)
A novel rhodium-catalyzed hydrophosphination of alkynes using a silylphosphine as a phosphino group source is described. A variety of alkynes, both terminal and internal ones with aryl, alkyl, and carboxyl groups, gave the corresponding alkenylphosphines in a highly regioselective and
Chemical Communications (Cambridge, England), 1359-1359 (2006)
New synthetic methods for olefins from secondary phosphates and thiophosphates
Shimagaki M, et al.
Tetrahedron Letters, 36, 719-719 (1995)
A mild procedure for etherification of alcohols with primary alkyl halides in the presence of silver triflate
Burk RM, et al.
Tetrahedron Letters, 35, 8111-8111 (1994)
B V Subba Reddy et al.
Organic letters, 15(3), 464-467 (2013-01-18)
A novel method has been devised for the synthesis of 2,4,5-trisubstituted pyrrole derivatives through the coupling of α-diazoketones with β-enaminoketones and esters using 10 mol % of Cu(OTf)(2). A wide range of 2,3-disubstituted indole derivatives were also prepared from α-diazoketones
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