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  • Solution-processable molecular cage micropores for hierarchically porous materials.

Solution-processable molecular cage micropores for hierarchically porous materials.

Advanced materials (Deerfield Beach, Fla.) (2012-08-30)
Tom Hasell, Haifei Zhang, Andrew I Cooper
ABSTRACT

Macroscopic inorganic porous beads are imbibed with a "porous molecular additive" by simple solution processing techniques, resulting in controllable loading and increased surface area. The porous additive consists of soluble organic cage molecules that precipitate as microporous crystals when solutions of opposite chirality are mixed.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Tetraethyl orthosilicate, SAJ first grade, ≥95.0%
Sigma-Aldrich
Tetraethyl orthosilicate, packaged for use in deposition systems
Sigma-Aldrich
Tetraethyl orthosilicate, ≥99.0% (GC)
Sigma-Aldrich
Tetraethyl orthosilicate, reagent grade, 98%
Sigma-Aldrich
Tetraethyl orthosilicate, 99.999% trace metals basis