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G307

Sigma-Aldrich

Galvinoxyl, free radical

Synonym(s):

2,6-Di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy, free radical

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About This Item

Empirical Formula (Hill Notation):
C29H41O2
CAS Number:
Molecular Weight:
421.63
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

mp

158-159 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)(C)c1cc(\C=C2\C=C(C(=O)C(=C2)C(C)(C)C)C(C)(C)C)cc(c1[O])C(C)(C)C

InChI

1S/C29H41O2/c1-26(2,3)20-14-18(15-21(24(20)30)27(4,5)6)13-19-16-22(28(7,8)9)25(31)23(17-19)29(10,11)12/h13-17H,1-12H3

InChI key

GNZDAXRYGVFYPU-UHFFFAOYSA-N

Application

Free radical and free-radical scavenger.

Storage Class Code

11 - Combustible Solids

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Donald B McPhail et al.
Journal of agricultural and food chemistry, 51(6), 1684-1690 (2003-03-06)
There is current interest in the use of naturally occurring flavonoids as antioxidants for the preservation of foods and the prevention of diseases such as atherosclerosis and cancers. To establish the molecular characteristics required for maximum antioxidant activity, electron spin
Lan-Fen Wang et al.
Bioorganic chemistry, 33(2), 108-115 (2005-03-25)
To improve the radical-scavenging activity of catechin, a planar catechin analogue was designed and synthesized by Fukuhara [J. Am. Chem. Soc. 124 (2002) 5952]. Although the planar catechin is less active than quercetin, it is much more active than catechin
Abolfazl Barzegar et al.
PloS one, 6(10), e26012-e26012 (2011-10-22)
Curcumin has many pharmaceutical applications, many of which arise from its potent antioxidant properties. The present research examined the antioxidant activities of curcumin in polar solvents by a comparative study using ESR, reduction of ferric iron in aqueous medium and
Lloyd L Lumata et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 227, 14-19 (2012-12-19)
The goal of this work was to test feasibility of using galvinoxyl (2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy) as a polarizing agent for dissolution dynamic nuclear polarization (DNP) NMR spectroscopy. We have found that galvinoxyl is reasonably soluble in ethyl acetate, chloroform, or acetone and
Jens Z Pedersen et al.
The Journal of pharmacy and pharmacology, 59(12), 1721-1728 (2007-12-07)
Polyphenolic coumarins are known to act as antioxidants in biological systems, but it is difficult to distinguish their antioxidant activity from the many other effects they produce in cells. We have determined the radical scavenging capacity of 22 structurally related

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