301868

4,7-Phenanthroline

98%

• Empirical Formula (Hill Notation): C₁₂H₈N₂
• CAS Number: 230-07-9
• Molecular Weight: 180.21
• MDL number: MFCD00004987
• UNSPSC Code: 12352100
• PubChem Substance ID: 24858214
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• mp: 172-174 °C (lit.)
• SMILES string: c1cnc2ccc3ncccc3c2c1
• InChI: 1S/C12H8N2/c1-3-9-10-4-2-8-14-12(10)6-5-11(9)13-7-1/h1-8H
• InChI key: DATYUTWESAKQQM-UHFFFAOYSA-N

Description

General description

4,7-Phenanthroline reacts with ruthenium carbonyl to yield cyclometalated derivatives.

Application

4,7-Phenanthroline was used in preparation of:

• cyclic tetranuclear half-sandwich ruthenium(II) complexes
• positively charged homochiral cyclic trinuclear metallacalix[3]arene species

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H302,H318
• Precautionary Statements: P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P501
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves