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Supelco

Bupirimate

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C13H24N4O3S
CAS Number:
Molecular Weight:
316.42
Beilstein:
758056
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCCCc1c(C)nc(NCC)nc1OS(=O)(=O)N(C)C

InChI

1S/C13H24N4O3S/c1-6-8-9-11-10(3)15-13(14-7-2)16-12(11)20-21(18,19)17(4)5/h6-9H2,1-5H3,(H,14,15,16)

InChI key

DSKJPMWIHSOYEA-UHFFFAOYSA-N

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General description

Bupirimate is an active ingredient in plant protection products and is commonly used as a systemic fungicide. It belongs to the family of pyrimidines and finds applications in controlling powdery mildew in roses and apple plantations.

Application

Bupirimate may be used as a reference standard in the determination of bupirimate in fruits using gas chromatography coupled with a flame photometric detector (GC-FPD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1B

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Detoxification of bupirimate pesticide in aqueous solutions by electrochemical oxidation
Errami.M, et al.
Der Pharm Chem, 4, 297-310 (2012)
chromatography/quadrupole-time-of-flight mass spectrometry},
Ernst.FG, et al.
Journal of Chromatography A, 179(2), 351-354 (1979)
Yun-Hui Teng et al.
Chang Gung medical journal, 27(12), 877-886 (2005-03-10)
The purpose of this retrospective study was to determine whether epidural fentanyl-bupivacaine patient-controlled analgesia (PCA) was more efficacious and had fewer adverse effects than epidural or intravenous morphine PCA. We retrospectively retrieved data from 859 patients (mean age 64+/-7 years)
Bupirimate--a new fungicide for the control of powdery mildews on apples and other crops
R.JF, et al.
Proceedings of the British Insecticide and Fungicide Conference (1975)
L J Fitzpatrick et al.
Journal of chromatography. A, 918(2), 429-433 (2001-06-16)
This paper assesses the effect of pressurised fluid extraction (PFE) on the recovery of bupirimate and its degradation product, ethirimol from a range of soil types. The analytes were extracted under standard conditions (pressure, 2000 p.s.i.; temperature, 100 degrees C;

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