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Metal-Organic Frameworks for fingermark detection - A feasibility study.

Forensic science international (2018-09-02)
Sébastien Moret, Esther Scott, Adrian Barone, Kang Liang, Chris Lennard, Claude Roux, Xanthe Spindler
RÉSUMÉ

Metal-Organic Frameworks (MOFs) are porous crystalline structures, currently used as sensors, separation membranes, and as catalysts. Due to their physicochemical and optical properties, they have been recently proposed for fingermark detection. This study further explored their potential for fingermark detection. Natural fingermarks, as well as charged and protein-enriched marks, were used to test the efficiency of the technique. Various parameters, such as precursor concentration, pH, immersion time and detection protocols, were investigated and optimised. The performance of the optimised MOF-based method was then compared to that of routinely used techniques. The results obtained indicated that MOFs can effectively detect fingermarks, especially protein-rich marks such as marks contaminated with body fluids. However, after comparison and evaluation against benchmark techniques, results were judged to be inferior to those from currently employed detection methods. However, with further research and optimisation MOFs may be promising as an alternative to current powder suspension techniques.

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Sigma-Aldrich
Terbium(III) chloride hexahydrate, 99.9% trace metals basis