701998

[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

98%

• Synonyme(s) : PdCl₂(dcypf)
• Formule empirique (notation de Hill): C₃₄H₅₂Cl₂FeP₂Pd
• Numéro CAS: 917511-90-1
• Poids moléculaire : 755.90
• Numéro MDL: MFCD11656081
• Code UNSPSC : 12161600
• ID de substance PubChem : 329762337
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Pureté: 98%
• Forme: powder
• Pertinence de la réaction: core: palladium; reagent type: catalyst
• Capacité de réaction: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• Pf: 294-300 °C
• Température de stockage: −20°C
• Chaîne SMILES: [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
• InChI: 1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
• Clé InChI: HRAMBTUEZQOQRK-UHFFFAOYSA-L

Description

Application

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl₂) can be used as a catalyst in the synthesis of:

• α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
• Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH₂ group and arylboronic acids.
• α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)