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Key Documents

A6756

Sigma-Aldrich

Sodium arsenate dibasic heptahydrate

≥98.0%

Synonym(s):

Disodium hydrogen arsenate heptahydrate, di-Sodium hydrogen arsenate heptahydrate

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About This Item

Linear Formula:
Na2HAsO4 · 7H2O
CAS Number:
Molecular Weight:
312.01
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

Assay

≥98.0%

form

powder

reaction suitability

reagent type: catalyst
core: arsenic

pH

8.5-9.0 (25 °C, 50 g/L)

SMILES string

O.O.O.O.O.O.O.[Na+].[Na+].O[As]([O-])([O-])=O

InChI

1S/AsH3O4.2Na.7H2O/c2-1(3,4)5;;;;;;;;;/h(H3,2,3,4,5);;;7*1H2/q;2*+1;;;;;;;/p-2

InChI key

KOLXPEJIBITWIQ-UHFFFAOYSA-L

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General description

Sodium arsenate dibasic heptahydrate (As(V)) is an arsenic compound.

Application

Sodium arsenate dibasic heptahydrate may be used as a reference standard for the quantification of arsenic compounds in rice- and seafood-based samples by ion chromatography-inductively coupled plasma/ mass spectrometry. The samples for analysis were prepared by ultrasonic-assisted enzymatic extraction (UAEE).

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Validation of a method for arsenic speciation in food by ion chromatography-inductively coupled plasma/mass spectrometry after ultrasonic-assisted enzymatic extraction.
Dufailly V, et al.
Journal of AOAC (Association of Official Analytical Chemists) International, 94(3), 947-958 (2011)
Martin P Pothier et al.
Frontiers in microbiology, 9, 2310-2310 (2018-10-20)
Despite its high toxicity and widespread occurrence in many parts of the world, arsenic (As) concentrations in decentralized water supplies such as domestic wells remain often unquantified. One limitation to effective monitoring is the high cost and lack of portability
Shugo Suzuki et al.
Toxicology, 299(2-3), 155-159 (2012-06-06)
Inorganic arsenic is a known human carcinogen, inducing tumors of the skin, urinary bladder and lung. It is metabolized to organic methylated arsenicals. 2,3-Dimercaptopropane-1-sulfonic acid (DMPS), a chelating agent, is capable of reducing pentavalent arsenicals to the trivalent state and
Joshua F Robinson et al.
Toxicology and applied pharmacology, 250(2), 117-129 (2010-10-05)
Arsenic (As) and cadmium (Cd) are well-characterized teratogens in animal models inducing embryotoxicity and neural tube defects (NTDs) when exposed during neurulation. Toxicological research is needed to resolve the specific biological processes and associated molecular pathways underlying metal-induced toxicity during
Karen D Bradham et al.
Environmental health perspectives, 119(11), 1629-1634 (2011-07-14)
Assessment of soil arsenic (As) bioavailability may profoundly affect the extent of remediation required at contaminated sites by improving human exposure estimates. Because small adjustments in soil As bioavailability estimates can significantly alter risk assessments and remediation goals, convenient, rapid

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