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Ambient-Stable Bis-Azoaromatic-Centered Diradical [(L

Inorganic chemistry (2017-10-14)
Sima Roy, Shuvam Pramanik, Sarat Chandra Patra, Basab Adhikari, Abhishake Mondal, Sanjib Ganguly, Kausikisankar Pramanik
ABSTRACT

Bis-azoaromatic electron traps, viz. 2-(2-pyridylazo)azoarene 1, have been synthesized by colligating electron-deficient pyridine and azoarene moieties, and they act as apposite proradical templates for the formation of stable open-shell diradical complexes [(1

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Sigma-Aldrich
Rhodium(III) chloride, 98%