The Critical Role of nπ* States in the Photophysics and Thermally Activated Delayed Fluorescence of Spiro Acridine-Anthracenone.

The molecular photophysics and thermally activated delayed fluorescence (TADF) in spiro compounds are distinct because of the rigid orthogonal C-C bridging bond between donor and acceptor. The photophysics is found to be highly complex, with unprecedented multiple anti-Kasha emissions from three different singlet states, two of which are one-photon forbidden. The TADF mechanism is critically controlled by local acceptor nπ* states; the singlet nπ* state undergoes rapid intersystem crossing populating an energetically close acceptor ππ* triplet state. The acceptor triplet nπ* state couples nonadiabatically to a CT triplet state mediating reverse intersystem crossing. When the nπ* and CT states are energetically close, TADF is greatly enhanced with rISC rate reaching 107 s-1. We observe neither DF from the singlet nπ* state nor electron transfer (ET) to form the 1CT because there is no ET driving force; however, ET from the higher-energy donor singlet ππ* state readily occurs along with donor emission.