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Graphene quantum point contact transistor for DNA sensing.

Proceedings of the National Academy of Sciences of the United States of America (2013-10-02)
Anuj Girdhar, Chaitanya Sathe, Klaus Schulten, Jean-Pierre Leburton
ABSTRACT

By using the nonequilibrium Green's function technique, we show that the shape of the edge, the carrier concentration, and the position and size of a nanopore in graphene nanoribbons can strongly affect its electronic conductance as well as its sensitivity to external charges. This technique, combined with a self-consistent Poisson-Boltzmann formalism to account for ion charge screening in solution, is able to detect the rotational and positional conformation of a DNA strand inside the nanopore. In particular, we show that a graphene membrane with quantum point contact geometry exhibits greater electrical sensitivity than a uniform armchair geometry provided that the carrier concentration is tuned to enhance charge detection. We propose a membrane design that contains an electrical gate in a configuration similar to a field-effect transistor for a graphene-based DNA sensing device.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Graphite, flakes
Sigma-Aldrich
Graphite, powder, <20 μm, synthetic
Sigma-Aldrich
Graphite, rod, L 150 mm, diam. 6 mm, 99.995% trace metals basis
Sigma-Aldrich
Graphite, powder, <150 μm, 99.99% trace metals basis
Sigma-Aldrich
Graphite, powder, <45 μm, ≥99.99% trace metals basis
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Graphite, rod, L 150 mm, diam. 3 mm, low density, 99.995% trace metals basis