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CRM05671

Supelco

Fenoxaprop-P-ethyl

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

Ethyl (R)-2-{4-[(6-chlorobenzoxazol-2-yl)oxy]phenoxy}propionate

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About This Item

Empirical Formula (Hill Notation):
C18H16ClNO5
CAS Number:
71283-80-2
Molecular Weight:
361.78
Beilstein:
8158010
MDL number:
MFCD01310637
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

300

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

2-8°C

SMILES string

CCOC(=O)[C@@H](C)Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1

InChI

1S/C18H16ClNO5/c1-3-22-17(21)11(2)23-13-5-7-14(8-6-13)24-18-20-15-9-4-12(19)10-16(15)25-18/h4-11H,3H2,1-2H3/t11-/m1/s1

InChI key

PQKBPHSEKWERTG-LLVKDONJSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fenoxaprop-P-ethyl (FPE) is a post-emergence herbicide that is used on many crops, such as rice, wheat, and barley, against annual and perennial grasses. It is an aryloxyphenoxypropionate that shows contact and systemic action. Fenoxaprop-P-ethyl works by inhibiting the activity of acetyl coenzyme A carboxylase and disrupting the synthesis of fatty acids. It is quickly converted to its metabolite fenoxaprop acid (FPA), another herbicidally active compound, in soil and plants. As per the commission regulation no 1107/2009, repealing the council directive 91/414/EEC unless otherwise stated the data available for fenoxaprop-P relates to its variant fenoxaprop-P-ethyl. It was approved for use in European Union on 1st January 2009 and the approval expires on 31st December 2022. According to Regulation (EC) no. 149/2008, a maximum residue limit (MRL) of 0.1 mg/kg applies for fenoxaprop-P in fresh/frozen fruits and tree nuts.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The CRM may also find the following uses:

  • Development and validation of gas chromatography (GC) and high-performance liquid chromatography (HPLC) method to detect FPE and its two primary metabolites in rice plants, rice straw, and rice grain
  • Study of the degradation of FPE and its metabolite in soil and wheat crops by high-performance liquid chromatography (HPLC) coupled with UV detector
  • Determination of FPE in barley and wheat grain samples using UV-Vis spectrophotometer
  • Residue analysis of FPE and its metabolite fenoxaprop acid using HPLC in the study to evaluate the persistence of the herbicide and its metabolite in soil, wheat grain, and straw
  • Development of a multi-residue enzyme-linked immunosorbent assay (ELISA) to detect two aryloxyphenoxypropionate herbicides in water, rice, soil, and soybean samples
  • Direct determination of FPE from water and crop samples by voltametric method and also analysis of its reduction behavior on a hanging mercury drop electrode (HMDE)

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Statements

H317,H373,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT RE 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF9304

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Detection of the herbicide fenoxaprop-P-ethyl, its agronomic safener isoxadifen ethyl and their metabolites residue in rice
Lucini L and Molinari G P
Quality Assurance and Safety of Crops & Foods, 3(2), 63- 68 (2011)
Reduction behavior of fenoxaprop-p-ethyl and its voltammetric determination
Es Zeki and Tasdemir ? H
Turkish Journal of Chemistry, 54- 63 null
Detection of aryloxyphenoxypropionate herbicides by enzyme-linked immunosorbent assay
Ren K, et al.
Analytical Letters, 831- 840 (2012)
Spectrophotometric method for the determination of fenoxaprop-p-ethyl herbicide in wheat and barley grains using charge transfer complex
Shehzad F N, et al.
Sarhad journal of agriculture, 28(1), 63- 68 (2012)
Shishir Tandon
Journal of food protection, 82(11), 1959-1964 (2019-10-23)
The dissipation kinetics of fenoxaprop-p-ethyl and its metabolite (fenoxaprop acid) at two application rates under wheat field conditions for two seasons was investigated. Herbicides were extracted by solid liquid extraction, cleaned up, and analyzed by a liquid chromatography-UV detector. Dissipation
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