Development of Membrane-Based Inverted Liquid-Liquid Extraction for the Simultaneous Extraction of Eight Metals in Seawater before ICP-OES Analysis.

In this work, we developed an extraction technique that can handle simple as well as complex matrixed liquid (aqueous) samples. In the standard liquid-liquid extraction, it is quite challenging to deal with complex liquid samples as they may complicate the process of phase separation and may lead to the formation of multiple layers. To resolve this issue, we have proposed a simple but unique idea that suggests the packing of the liquid samples inside a porous membrane bag. The edges of the membrane bag can be sealed using an electrical heat-sealer. The porous membrane bag filled with the liquid sample was immersed in an extraction solvent, and the extraction process was assisted by mechanical shaking. In order to demonstrate the proof of concept, a method was developed for the extraction of metals from seawater samples. The pH-adjusted sample, along with the complexing reagent, was packed inside the porous membrane bag, and the chelated complex was then extracted by immersing and shaking the bag inside the organic solvent. The solvent was then evaporated, and the chelated complex was dissolved/digested in acid with the aid of the heat. The final extract was subjected to Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) analysis. The proposed method was used for extraction of eight metals (Cd, Co, Cu, Mo, Ni, Pb, V and Zn) from seawater samples and good extraction recoveries (75-94%) were obtained.