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223301

Trioctylphosphine oxide

99%, solid, ReagentPlus®

Caractéristiques en matière de développement durable

Synonyme(s) :

(Oct)3PO, TOPO®

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5 g

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A propos de cet article

Formule linéaire :
[CH3(CH2)7]3PO
Numéro CAS:
Poids moléculaire :
386.63
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352119
EC Number:
201-121-3
MDL number:
Beilstein/REAXYS Number:
1796648

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Nom du produit

Trioctylphosphine oxide, ReagentPlus®, 99%

Quality Segment

product line

ReagentPlus®

assay

99%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Sustainability features

bp

201-202 °C/2 mmHg (lit.)

mp

50-52 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

ZMBHCYHQLYEYDV-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Used to extract metals and hydrogen bonding organic compounds. For a review of industrial applications.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
TOPO is a registered trademark of Life Technologies

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Cet article
00676346187735914
description

ReagentPlus®, 99%

description

for extraction analysis, ≥98.5%

description

technical grade, 90%

description

97%

reaction suitability

reagent type: ligand, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reagent type: ligand

reaction suitability

-

reaction suitability

-

assay

99%

assay

≥98.5% (GC)

assay

90%

assay

97%

functional group

phosphine

functional group

phosphine oxide

functional group

phosphine oxide

functional group

-

form

solid

form

-

form

solid

form

solid

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

bp

201-202 °C/2 mmHg (lit.)

bp

201-202 °C/2 mmHg (lit.)

bp

201-202 °C/2 mmHg (lit.)

bp

-


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Pictogrammes

Corrosion

Mot-clé

Danger

Codes de danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

Classe de stockage

11 - Combustible Solids

Que se passe-t-il ?

WGK 3

Point d'éclair (°F)

446.0 °F - closed cup

Point d'éclair (°C)

230 °C - closed cup

EPI (équipement de protection individuelle)

dust mask type N95 (US), Eyeshields, Gloves



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Certificats d'analyse (COA)

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Questions

1–2 sur 2 questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 réponse
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 réponse
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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