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  • A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion.

A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion.

Dalton transactions (Cambridge, England : 2003) (2009-01-06)
Masahiko Maekawa, Atsuhiro Nabei, Toshi Tominaga, Kunihisa Sugimoto, Toshie Minematsu, Takashi Okubo, Takayoshi Kuroda-Sowa, Megumu Munakata, Susumu Kitagawa
ABSTRACT

Three novel Cu(I)-C2H4 adducts bearing 4-(2-pyridyl)pyrimidine were self-assembled, and the roles of anion and solvent were proved in the formation process.

MATERIALS
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Product Description

Supelco
Boron trifluoride - 1-butanol solution, ~10% in 1-butanol (∼1.3 M), for GC derivatization, LiChropur