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249998

Sigma-Aldrich

Titanium(III) chloride solution

~10 wt. % in 20-30 wt. % hydrochloric acid

Synonym(s):

Titanium trichloride

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About This Item

Linear Formula:
TiCl3
CAS Number:
Molecular Weight:
154.23
MDL number:
UNSPSC Code:
12352301
PubChem Substance ID:

reaction suitability

reagent type: catalyst
core: titanium

concentration

~10 wt. % in 20-30 wt. % hydrochloric acid

density

1.192 g/mL at 25 °C

SMILES string

Cl[Ti](Cl)Cl

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

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Application

Catalyst for:
Hydrogen desorption properties[1]
Nitrogen-nitrogen reductive bond cleavage[2]

Reagent for:
Photocatalyst synthesis[3]
Preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeleton[4]

Other Notes

Exact concentration stated on label

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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S. Isobe, et al.,
Applied Physics Letters, 99 (2011)
Shuxi Dai et al.
Nanoscale research letters, 5(11), 1829-1835 (2010-12-03)
Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy
D. Meroni, et al
Catalysis Today, 161, 169-174 (2011)
L Messori et al.
FEBS letters, 442(2-3), 157-161 (1999-02-03)
The reaction of human serum apotransferrin with titanium(IV) citrate under physiological conditions results in the formation of a specific bis-titanium(IV) transferrin adduct (Ti2Tf hereafter) with two titanium(IV) ions loaded at the iron binding sites. The same specific Ti2Tf complex is
Palaniappan Kulanthaivel et al.
Drug metabolism and disposition: the biological fate of chemicals, 32(9), 966-972 (2004-08-21)
Phase I oxidative metabolism of nitrogen-containing drug molecules to their corresponding N-oxides is a common occurrence. There are instances where liquid chromatography/tandem mass spectometry techniques are inadequate to distinguish this pathway from other oxidation processes, including C-hydroxylations and other heteroatom

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