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  • Morpholine catalyzed direct C3 alkenylation of indoles with α,β-unsaturated aldehydes.

Morpholine catalyzed direct C3 alkenylation of indoles with α,β-unsaturated aldehydes.

Chemical communications (Cambridge, England) (2011-06-21)
Shi-Kai Xiang, Bo Zhang, Li-He Zhang, Yuxin Cui, Ning Jiao
ABSTRACT

Organocatalytic direct C3 alkenylation of indoles has been developed. Simple and readily available morpholine trifluoroacetic acid salt is employed as an efficient catalyst in this oxidative dehydrogenative reaction. Simplicity and practicality constitute the most attractive advantages of this reaction.

MATERIALS
Product Number
Brand
Product Description

Supelco
Morpholine, analytical standard
Sigma-Aldrich
Morpholine, ReagentPlus®, ≥99%
Sigma-Aldrich
Morpholine, purified by redistillation, ≥99.5%
Sigma-Aldrich
Morpholine, ACS reagent, ≥99.0%