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535834

Sigma-Aldrich

Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate

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About This Item

Empirical Formula (Hill Notation):
C28H52N2O4
CAS Number:
52829-07-9
Molecular Weight:
480.72
EC Number:
258-207-9
MDL number:
MFCD00134709
UNSPSC Code:
12162002
PubChem Substance ID:
24878106
NACRES:
NA.23

loss

0.7 wt. % volatility, 150-175°C

mp

82-85 °C (lit.)

transition temp

Tg >350 °C (dec)

solubility

acetone: 19 % (w/w) at 20 °C
ethyl acetate: 24 % (w/w) at 20 °C
methanol: 38 % (w/w) at 20 °C
chloroform: 45 % (w/w) at 20 °C
methylene chloride: 56 % (w/w) at 20 °C
H2O: insoluble <6 ppm at 20 °C

SMILES string

CC1(C)CC(CC(C)(C)N1)OC(=O)CCCCCCCCC(=O)OC2CC(C)(C)NC(C)(C)C2

InChI

1S/C28H52N2O4/c1-25(2)17-21(18-26(3,4)29-25)33-23(31)15-13-11-9-10-12-14-16-24(32)34-22-19-27(5,6)30-28(7,8)20-22/h21-22,29-30H,9-20H2,1-8H3

InChI key

XITRBUPOXXBIJN-UHFFFAOYSA-N

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General description

Bis(2,2,6,6-tetramethyl-4-piperidyl) (T770) sebacate is a low molecular weight ultra violet (UV) hindered amine light stabilizer (HALS) made up of nitroxyl radicals. It acts as a heat controller that can react with phenolic antioxidants incorporated in polymers.

Application

T770 can be used as a hindered amine UV stabilizer in plastic materials. It can be used in the manufacturing and packaging of pharmaceutical products. Titanium oxide(TiO2)/T770 may be used in amine induced light stabilizers in the synthesis of recyclable water-based polyurethane with poly(oxytetramethylene)glycol (PTMG).

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H318,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

>302.0 °F

Flash Point(C)

> 150 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Brandon J Hall et al.
Neuroscience letters, 474(2), 84-87 (2010-03-17)
Withdrawal from cocaine use often is associated with anxiety and depressive states. In this study the use-dependent, nicotinic acetylcholine receptor antagonist bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate (BTMPS) was studied for its ability to reduce these symptoms in two rat models of anxiety and
H Glossmann et al.
Proceedings of the National Academy of Sciences of the United States of America, 90(20), 9523-9527 (1993-10-15)
A pharmacologically active agent was easily extracted by aqueous or organic solvents from laboratory plastic tubes (Falcon Blue Max) and has been chemically identified as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate. This compound (approximately 12 micrograms per tube approximately 25 nmol) blocked 1,4-dihydropyridine-sensitive 45Ca2+
V Jackson-Lewis et al.
Brain research, 866(1-2), 197-210 (2000-05-29)
Tinuvin 123, a compound used in the manufacture of plastics, has recently been suggested to possibly cause Parkinson's disease (PD). Herein, we revisited this issue by assessing the effect of Tinuvin 123 on dopaminergic neurons of the substantia nigra following
Brandon J Hall et al.
Neuropharmacology, 58(2), 429-435 (2009-09-24)
The use-dependent, nicotinic acetylcholine receptor antagonist bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate (BTMPS) was studied for its potential to reduce the self-administration of nicotine in rats, as well as to reduce context-induced recidivistic-like behavior after a six-week period of cessation. Rats were allowed to
R L Papke et al.
The Journal of pharmacology and experimental therapeutics, 268(2), 718-726 (1994-02-01)
Bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacate (BTMPS; Tinuvin 770), a sterically hindered amine light and radiation stabilizer manufactured by Ciba-Geigy Corp. (Summit, NJ) and used in a wide range of plastics, inhibits nicotinic acetylcholine receptors expressed in Xenopus oocytes in a use-dependent manner.
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