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HPLC Analysis of Cosmetic Preservatives on Ascentis® Express RP-Amide

HPLC Analysis of Cosmetic Preservatives on Ascentis® Express RP-Amide application for HPLC

Materials

analytical column

Product No.
Description
Pricing

Ascentis® Express RP-Amide, 2.7 μm HPLC Column

2.7 μm particle size, L × I.D. 10 cm × 3 mm

standard

Product No.
Description
Pricing

2-Phenoxyethanol

analytical standard

1-Phenoxy-2-propanol

≥93%

Benzyl 4-hydroxybenzoate

99%

Methyl Paraben

PESTANAL®, analytical standard

Ethylparaben

United States Pharmacopeia (USP) Reference Standard

Propylparaben

United States Pharmacopeia (USP) Reference Standard

CONDITIONS

column

Ascentis Express RP-Amide, 10 cm x 3 mm I.D., 2.7 μm particles (53918-U)

mobile phase

[A] water; [B] methanol; (60:40, A:B)

flow rate

0.6 mL/min

pressure

2900 psi (200 bar)

column temp.

50 °C

detector

UV, 250 nm

injection

1 μL

sample

methyl-, benzylparaben (50 mg/L), ethylparaben (30 mg/L), propyl-, butylparaben (100 mg/L), 2-phenoxyethanol (1.5 g/L),1-phenoxy-2-propanol (3 g/L), all in 40% methanol

Description

Analysis Note

With the publication Borremans, M. et.al. 2004, Chromatographia 59: 47-53 as a reference, this method is 10% faster, but with superior resolution of critical pairs; in this case, the minimum USP resolution is 2.4.

Legal Information

Ascentis is a registered trademark of Merck KGaA, Darmstadt, Germany