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  • A highly active and magnetically retrievable nanoferrite-DOPA-copper catalyst for the coupling of thiophenols with aryl halides.

A highly active and magnetically retrievable nanoferrite-DOPA-copper catalyst for the coupling of thiophenols with aryl halides.

Chemical communications (Cambridge, England) (2012-02-02)
R B Nasir Baig, Rajender S Varma
ABSTRACT

Diaryl sulfides were synthesized using a magnetically recoverable heterogeneous Cu catalyst via one-pot multi component reaction using MW irradiation; the use of isopropanol as a benign reaction medium, easy recovery of the catalyst using an external magnet, efficient recycling, and the high stability of the catalyst render the protocol economic and sustainable.

MATERIALS
Product Number
Brand
Product Description

Supelco
Thiophenol, analytical standard
Sigma-Aldrich
Thiophenol, ≥99%
Sigma-Aldrich
Thiophenol, 97%
Sigma-Aldrich
Sodium thiophenolate, technical grade, 90%
Sigma-Aldrich
Chlorobenzene, anhydrous, 99.8%
Supelco
Chlorobenzene, analytical standard
Sigma-Aldrich
Chlorobenzene, suitable for HPLC, 99.9%
Sigma-Aldrich
Chlorobenzene, ACS reagent, ≥99.5%