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92768

Sigma-Aldrich

(Trimethylsilyl)methylamine

≥98.0% (GC)

Synonym(s):

(Aminomethyl)trimethylsilane

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About This Item

Empirical Formula (Hill Notation):
C4H13NSi
CAS Number:
18166-02-4
Molecular Weight:
103.24
Beilstein:
1731488
EC Number:
242-049-2
MDL number:
MFCD00042931
UNSPSC Code:
12352100
PubChem Substance ID:
57653491
NACRES:
NA.22
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Quality Level

100

Assay

≥98.0% (GC)

form

liquid

refractive index

n20/D 1.416

bp

92-94 °C (lit.)

density

0.771 g/mL at 20 °C (lit.)

functional group

amine

SMILES string

C[Si](C)(C)CN

InChI

1S/C4H13NSi/c1-6(2,3)4-5/h4-5H2,1-3H3

InChI key

YVWPNDBYAAEZBF-UHFFFAOYSA-N

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Other Notes

Synthesis of trimethylsilyl-diazomethane[1]; 1,3-Cycloaddition of its imine[2]; preparation of azomethine ylides from ketones[3]

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H225,H314

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

48.2 °F - closed cup

Flash Point(C)

9 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM3226
BCCK6288
BCCK3986
BCBW1911
BCBT5086

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M. Letellier et al.
Synthetic Communications, 18, 1975-1975 (1988)
K. Achiwa et al.
Chemical & Pharmaceutical Bulletin, 31, 3939-3939 (1983)
D. Seyferth et al.
Journal of Organometallic Chemistry, 44, 279-279 (1972)

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