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Merck

Adsorptive removal of bisphenol-A from water with a metal-organic framework, a porous chromium-benzenedicarboxylate.

Journal of nanoscience and nanotechnology (2013-06-15)
Eun Young Park, Zubair Hasan, Nazmul Abedin Khan, Sung Hwa Jhung
RESUMEN

Adsorptive removal of bisphenol-A (BPA) using a MOF, Cr-benzenedicarboxylate (MIL-53), has been studied to understand the applicability of MOFs for the removal of hazardous endocrine disturbing chemicals from water. MIL-53 shows very fast adsorption in an hour and the adsorption capacity of MIL-53 is higher than that of activated carbon. Importantly, the adsorption of BPA over MIL-53 is very favorable especially at very low concentrations of BPA. Therefore, MOFs such as MIL-53 can be one of adsorbents that may be used in the adsorptive removal of BPA from contaminated water.

MATERIALES
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Sigma-Aldrich
Benceno, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Benceno, ACS reagent, ≥99.0%
Supelco
Bisphenol A, ≥99%
Sigma-Aldrich
Benceno, puriss. p.a., reag. Ph. Eur., ≥99.7%
Supelco
Benzene solution, certified reference material, TraceCERT®, 200 μg/mL in methanol
Sigma-Aldrich
Bisphenol A, 97%
Sigma-Aldrich
Chromium, powder, ≥99% trace metals basis, <45 μm
Supelco
Benceno, analytical standard
Sigma-Aldrich
Benceno, anhydrous, 99.8%
Sigma-Aldrich
Chromium, powder, 99.5%, −100 mesh
Sigma-Aldrich
Chromium, chips, 99.995% trace metals basis
Sigma-Aldrich
Chromium, chips, thickness ~2 mm, 99.5%
Supelco
Benceno, Pharmaceutical Secondary Standard; Certified Reference Material