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Merck

Transfer of eight phthalates through the milk chain--a case study.

Environment international (2012-11-10)
T Fierens, M Van Holderbeke, H Willems, S De Henauw, I Sioen
RESUMEN

This survey determined the levels of eight phthalates - i.e. dimethyl phthalate (DMP), diethyl phthalate (DEP), diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), benzylbutyl phthalate (BzBP), di(2-ethylhexyl) phthalate (DEHP), dicyclohexyl phthalate (DCHP) and di-n-octyl phthalate (DnOP) - in several Belgian milk and dairy products. Samples were obtained from various farms, a dairy factory and from different shops in order to investigate phthalate contamination "from farm to fork". At several stages in the milk chain, product contamination with phthalates - mostly DiBP, DnBP, BzBP and DEHP - was observed. At farm level, the mechanical milking process and the intake of phthalate containing feed by the cattle were found to be possible contamination sources. At industry and retail level, contact materials including packaging materials were additional contamination sources for phthalates in milk and dairy products.

MATERIALES
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Dibutyl phthalate, 99%
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Dioctyl phthalate, ≥99.5%
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Diethyl phthalate, 99.5%
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Dimethyl phthalate, ≥99%
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Dicyclohexyl phthalate, 99%
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Potassium phthalate monobasic, BioXtra, ≥99.95%
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Diisobutyl phthalate, 99%
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Diethyl phthalate, ≥99%
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Phthalic acid, ACS reagent, ≥99.5%
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Dioctyl phthalate, ≥98.0% (GC)
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Potassium phthalate monobasic, reference material for titrimetry, certified by BAM, >99.5%
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Potassium phthalate monobasic, ACS reagent, acidimetric standard
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Dimethyl phthalate, ≥99%
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Potassium phthalate monobasic, puriss. p.a., ≥99.5% (T)
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Potassium phthalate monobasic, BioUltra, ≥99.5% (T)
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Bis(2-ethylhexyl) phthalate, PESTANAL®, analytical standard
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Bis(2-ethylhexyl) phthalate solution, certified reference material, 2000 μg/mL in methanol
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Bis(2-ethylhexyl) phthalate, Selectophore
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Dibutyl phthalate, PESTANAL®, analytical standard
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Di-n-butyl phthalate solution, certified reference material, 5000 μg/mL in methanol
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Bis(2-ethylhexyl) phthalate, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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Phthalic acid, puriss. p.a., ≥99.5% (T)
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Phthalic acid dipotassium salt, 98%
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Dimethyl phthalate, PESTANAL®, analytical standard
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Diethyl phthalate, PESTANAL®, analytical standard
Supelco
Dioctyl phthalate, analytical standard
Sigma-Aldrich
Phthalic acid, reagent grade, 98%
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Potassium phthalate monobasic, Standard for quantitative NMR, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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Diisobutyl phthalate, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Supelco
Dibutyl phthalate, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland